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- W1963670552 abstract "A new method for determining activity coefficients at infinite dilution from dew point and/or bubble point data in binary systems is proposed. The extrapolated values of dew point and bubble point parameters, respectively, defined as D≡ a1a2/(1 - a1) (1 - a2) and B≡ (1 - b1) (1 - b2)/b1b2, agree thermodynamically with the activity coefficients at infinite dilution. The values of ''a'' and ''b'', respectively, can be calculated by a≡ γ× = (π/P)y from dew point data and by b≡ (y/γ) = (P/π)× from bubble point data, where x, y, P, π and γ, respectively, express mole fraction in liquid phase, that in vapor phase, vapor pressure, total pressure and activity coefficient." @default.
- W1963670552 created "2016-06-24" @default.
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- W1963670552 date "1970-01-01" @default.
- W1963670552 modified "2023-10-11" @default.
- W1963670552 title "DETERMINATION OF ACTIVITY COEFFICIENTS AT INFINITE DILUTION FROM DEW POINT AND/OR BUBBLE POINT CURVES" @default.
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- W1963670552 doi "https://doi.org/10.1252/jcej.3.1" @default.
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