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• W1963677892 abstract "The crystal structure of La(H2O)2K(C2O4)2·H2O has been solved ab initio from powder diffraction data collected with conventional monochromatic X-rays. The symmetry is monoclinic, space group C2/m, cell dimensions a=22.033(1) Å, b=7.6003(5) Å, c=6.6418(4) Å, β=103.814(6)°, V=1080.05(8) Å3, Z=4. Since a disorder of one oxalate group is observed with all possible monoclinic space groups, it has been found convenient to describe the crystal structure in a triclinic subcell. The disorder problem is thoroughly discussed with respect to the powder diffraction data available for this material. From this description the compound exhibits a layered-type structure, which could explain reported cation-exchange properties. The layers are formed by four-membered rings [La(C2O4)]4. The potassium atom and two of the three water molecules are located between the layers. The third water molecule lies on the layer in tunnels with a diamond-shaped cross section. The lanthanum atom is tenfold-coordinated in a distorted bicapped square antiprism and the potassium atom is eightfold-coordinated in a dodecahedron. The crystal structure of La(H2O)2(NH4)(C2O4)2·H2O is isostructural with that of La(H2O)2K(C2O4)2·H2O [a=22.130(4) Å, b=7.774(1) Å, c=6.655(2) Å, β=105.28(2)°, V=1104.4(3) Å3]. The thermal decomposition of these two precursors has been carried out by means of temperature-dependent X-ray diffraction and TG-DSC. The dehydration leads to anhydrous phases, which are amorphous and poorly crystalline for the potassium and ammonium compounds, respectively. Amorphous LaK(C2O4)2 crystallizes at 260°C. Its symmetry is monoclinic with the cell dimensions a=5.687(3) Å, b=15.241(5) Å, c=9.017(4) Å, β=92.82(3)°. At higher temperature, the decomposition of LaK(C2O4)2 yields La2O2CO3 (Type-Ia), La2O2CO3 (Type-II), and pure La2O3, successively. La(NH4)(C2O4)2 leads to La2O2CO3 (Type-II) and, finally, La2O3." @default.
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• W1963677892 date "2000-02-01" @default.
• W1963677892 modified "2023-09-30" @default.
• W1963677892 title "Crystal Structure and Thermal Behavior of La(H2O)2M(C2O4)2·H2O (M=K, NH4) Studied by Powder X-Ray Diffraction" @default.
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• W1963677892 doi "https://doi.org/10.1006/jssc.1999.8550" @default.
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