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- W1963678633 abstract "In the chromatographic separation of natural and synthetic polymers, the retention and peak broadening are strongly dependent on the sample size. Contrary to chromatography of low-molecular-weight solutes, no linear region was observed where both factors are independent of sample size. Even in gradient elution, proteins are eluted approximately 3% of the gradient time earlier when the sample size is increased by a factor of ten. With non-porous materials of small particle diameters and small surface areas, the peak broadening is markedly affected by sample size. Their advantage in efficiency compared to standard porous materials is lost at sample sizes around 100 μg. Generally, retention decreases with increasing sample size, but also the contrary has been observed. In precipitation chromatography of polystyrenes similar behaviour has been observed. Consequently, one has to be careful in qualitative identifications of polymers in mixtures of unknown concentrations and in the transfer of analytical results to preparative-scale work." @default.
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- W1963678633 date "1988-12-01" @default.
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- W1963678633 title "Sample size and retention values in high-performance liquid chromatography of biological and synthetic polymers" @default.
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- W1963678633 doi "https://doi.org/10.1016/s0021-9673(00)90555-7" @default.
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