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• W1963707260 abstract "The interactions of several porphyrins with a 74 base-pair DNA sequence have been examined by footprinting and chemical protection methods. Tetra-(4-N-methyl-(pyridyl)) porphyrin (TMPy), two of its metal complexes and tetra-(4-trimethylanilinium) porphyrin (TMAP) bind to closely similar AT-rich sequences. The three TMPy ligands produce modest changes in DNA structure and base accessibility on binding, in contrast to the large-scale conformational changes observed with TMAP. Molecular modelling studies have been performed on TMPy and TMAP bound in the AT-rich minor groove of an oligonucleotide. These have shown that significant structural change is needed to accommodate the bulky trimethyl substituent groups of TMAP, in contrast to the facile minor groove fit of TMPy." @default.
• W1963707260 created "2016-06-24" @default.
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• W1963707260 date "1995-06-01" @default.
• W1963707260 modified "2023-09-28" @default.
• W1963707260 title "Perturbations in DNA structure upon interaction with porphyrins revealed by chemical probes, DNA footprinting and molecular modelling" @default.
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• W1963707260 doi "https://doi.org/10.1016/0968-0896(95)00052-i" @default.
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• W1963707260 hasPublicationYear "1995" @default.
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