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- W1963707966 abstract "Values for the solubility of silver benzoate and silver salicylate in equimolar solutions of sodium perchlorate and perchloric acid in four different compositions of water + urea (11.52, 20.31, 29.64 and 36.83 wt.%) mixtures have been determined at 15, 25, 35 and 45°C. From the solubility values in sodium perchlorate solutions, thermodynamic solubility products of the silver salts have been evaluated, and in perchloric acid solutions the thermodynamic dissociation constants of benzoic and salicyclic acids have been determined in water + urea mixtures. Solubility data have been discussed in the light of electrostatic as well as solute—solvent interaction effects on the dissolution processes of silver salts. Standard transfer thermodynamic quantities derived from the change in the solubility product are also examined. Standard potentials of the silver—silver benzoate and silver—silver salicylate electrodes have also been evaluated in these mixed solvents." @default.
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- W1963707966 date "1988-10-01" @default.
- W1963707966 modified "2023-10-14" @default.
- W1963707966 title "Solute—solvent interactions: dissolution of silver benzoate and silver salicylate in water + urea mixtures" @default.
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- W1963707966 doi "https://doi.org/10.1016/0378-3812(88)80027-x" @default.
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