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- W1963759675 abstract "[reaction: see text] We have found a new synthetic method for the preparation of the alpha-bromoketones that are brominated in the less activated terminal position of unsymmetrical ketones. Brominations in short reaction times (kinetically controlled) provided internally brominated compounds as a major product. However, brominations in longer reaction times (thermodynamically controlled) gave more of the terminally brominated compound through the reversible reaction by Br(2) and produced hydrogen bromide. Several brominated compounds at the terminal position were successfully prepared through the new synthetic route." @default.
- W1963759675 created "2016-06-24" @default.
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- W1963759675 date "2003-01-21" @default.
- W1963759675 modified "2023-09-26" @default.
- W1963759675 title "Nonselective Bromination−Selective Debromination Strategy: Selective Bromination of Unsymmetrical Ketones on Singly Activated Carbon against Doubly Activated Carbon" @default.
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- W1963759675 doi "https://doi.org/10.1021/ol0271638" @default.
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