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• W1963766215 abstract "The simple and highly enantioselective methanolysis of norbornene dicarboxylic acid anhydride mediated by quinidine leads to the corresponding cis-monomethyl ester with 98% ee. By means of selective ester epimerization, followed by Curtius degradation of the intermediate trans-diacyl azide, two optically active norbornane-type diamines are obtained as their hydrochloric salts. Liberating the amine with an excess of triethylamine in situ and subsequent derivatization affords potential C1-symmetric ligands for asymmetric catalysis in excellent yields." @default.
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• W1963766215 date "2002-10-24" @default.
• W1963766215 modified "2023-10-16" @default.
• W1963766215 title "A novel asymmetric synthesis of highly enantiomerically enriched norbornane-type diamine derivatives" @default.
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• W1963766215 doi "https://doi.org/10.1039/b206943c" @default.
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