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- W1963792692 abstract "Extended X-ray Absorption Fine Structure (EXAFS) spectroscopic data for Cd 2+ sorbed on goethite in the presence of phosphate, sulphate and humate indicate that cadmium is surrounded by a first shell of ∼6 ± 1 O atoms at 2.3 ± 0.1 Å. A second shell of approximately 2 Fe atoms at 3.8 ± 0.1 Å is also observed. These interatomic distances suggest that Cd 2+ is inner-spherically bound by bidentate double-corner-sharing adsorption on the (110) surface of goethite. In contrast, Cd 2+ appears to form a precipitate in the presence of citrate and oxalate. The enhancement of Cd 2+ adsorption in the presence of sulphate and phosphate is solely by electrostatic interaction, implying that the ligands sorb to sites other than those occupied by Cd 2+ . No ternary complexes are observed in the presence of these 2 inorganic ligands." @default.
- W1963792692 created "2016-06-24" @default.
- W1963792692 creator A5026090313 @default.
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- W1963792692 date "1999-10-01" @default.
- W1963792692 modified "2023-10-17" @default.
- W1963792692 title "Effect of inorganic and organic ligands on the mechanism of cadmium sorption to goethite" @default.
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- W1963792692 doi "https://doi.org/10.1016/s0016-7037(99)00226-4" @default.
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