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- W1963818360 abstract "TiO2 powder in either the rutile or the anatase form do not generate ammonia when they are subjected to ultraviolet irradiation under a wet nitrogen flux. In order to undergo this photochemical reaction, the samples first have to be annealed under air at atmospheric, high temperature. This treatment generates defect states in the band gap of the semiconductor and in the hydroxyl groups on the surface. The effects of thermal pretreatment on the various characteristics of the TiO2 powders such as specific area, crystal structure, morphology and stoichiometry have been studied. The nature of the hydroxyl groups on TiO2 surface is determined by IR spectrometry and by temperature-programmed desorption." @default.
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- W1963818360 date "1988-10-01" @default.
- W1963818360 modified "2023-09-26" @default.
- W1963818360 title "A study of TiO2 powders as a support for the photochemical synthesis of ammonia" @default.
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- W1963818360 doi "https://doi.org/10.1016/0168-7336(88)80048-2" @default.
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