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- W1963827767 abstract "A novel application of a commercial photoionization detector for the quantification of argon is described and applied to the headspace analysis of water. Using an argon lamp as the excitation source, argon is measured indirectly by its effect on an ionizable gas present in the detection cell. Nitric oxide is added to the effluent of a gas chromatography column, resulting in an elevated background ion current in a photoionization detector. By varying the amount of nitric oxide added to the detection cell, two modes of operation were demonstrated: a competitive absorbance mode in which a high background of nitric oxide photoionization was reduced in response to the presence of argon and a Penning ionization mode in which a relatively lower background of nitric oxide photoionization was enhanced in response to the presence of argon. Optimized Penning ionization detection with a nitric oxide concentration at ∼940 ppmv was used to analyze air and the headspace of water samples. The limit of detection was dete..." @default.
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- W1963827767 date "1998-07-03" @default.
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- W1963827767 title "Detection of Argon by Penning Ionization and Competitive Absorption Using a Sensitized Photoionization Detector" @default.
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- W1963827767 doi "https://doi.org/10.1021/ac9802022" @default.
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