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- W1963840011 abstract "Luminescence spectra are recorded for collisions between Xe+/Xe2+ and molecular nitrogen at energies ranging from 4.5 to 316 eV in the center-of-mass frame. In the Xe+ + N2 collision system, evidence for luminescent charge-transfer products is only found through Xe I emission lines. The most intense features of the luminescence spectra are attributed to atomic N emissions observed above ∼20 eV. Intense N2+ A 2Πu − X2Σg+ and B2Σu+ − X2Σg+ radiance is observed from Xe2+ + N2 collisions. The B state formation cross section decreases with collision energy until 20 eV, after which it becomes independent of impact energy with an approximate value of 3 Å2. The cross section for N2+ A (v > 0) formation increases with energy until 20 eV, after which it remains nearly constant at ∼1 Å2. The N2+ product vibrational distributions extracted from the spectra are non-Franck-Condon for both electronic product states at low collision energies. The distributions resemble a Franck-Condon distribution at the highest energies investigated in this work." @default.
- W1963840011 created "2016-06-24" @default.
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- W1963840011 date "2011-09-14" @default.
- W1963840011 modified "2023-10-18" @default.
- W1963840011 title "Luminescence measurements of Xe<sup>+</sup>+ N<sub>2</sub>and Xe<sup>2+</sup>+ N<sub>2</sub>hyperthermal charge transfer collisions" @default.
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- W1963840011 doi "https://doi.org/10.1063/1.3629453" @default.
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