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- W1963851078 abstract "We recapitulate and generalize the concept of the freezing-melting hysteresis that attributes this phenomenon to a free-energy barrier between metastable and stable states of pore-filling material. In a phenomenological description, we show that under commonly encountered conditions, this renders the freezing-point depression $ensuremath{Delta}{T}_{f}$ defined by the surface-to-volume ratio $S∕V$, whereas the melting-point depression $ensuremath{Delta}{T}_{m}$ by the mean curvature $ensuremath{kappa}$ of the pore surface, with $ensuremath{Delta}{T}_{m}∕ensuremath{Delta}{T}_{f}=2ensuremath{kappa}(V∕S)$. Employing $^{1}mathrm{H}$ NMR cryoporometry, we experimentally demonstrate the linear correlation between $ensuremath{Delta}{T}_{m}$ and $ensuremath{Delta}{T}_{f}$ for several liquids with different $ensuremath{Delta}{T}_{f,m}$ imbibed in controlled pore glasses. The results compare favorably to the morphological properties of the glasses determined by other techniques. Our findings suggest a simple method for analyzing the pore morphology from the observed phase transition temperatures." @default.
- W1963851078 created "2016-06-24" @default.
- W1963851078 creator A5061981173 @default.
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- W1963851078 date "2006-01-31" @default.
- W1963851078 modified "2023-10-16" @default.
- W1963851078 title "Curvature-dependent metastability of the solid phase and the freezing-melting hysteresis in pores" @default.
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- W1963851078 doi "https://doi.org/10.1103/physreve.73.011608" @default.
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