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- W1963876762 abstract "Abstract Advantage is taken of the property that activated charcoal particles dispersed in a solution accumulate on the HMDE. Alternating current voltammetry is used to determine the surface area of carbon sticking to the electrode on which redox processes may proceed. The surface area of charcoal determined in this way allowed us to estimate the contents of electroactive oxygen in three types of carbon samples. It has been found that the capability of carbon particles to stick to the mercury surface increases with growing oxygen content. The electroactive forms of oxygen bonded to the carbon surface undergo reduction in a peak at about −0.5 V. The second reduction peak, at about −1.6 V, is connected with hydrogen evolution on the charcoal-covered part of the electrode. Detachment of the charcoal particles from the mercury surface results in decay of the H 3 O + reduction current. Photographs provide evidence of the efficiency of accumulation of the carbon particles in dependence on the type of sample tested and the HMDE potential as well as phenomena accompanying “desorption”." @default.
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- W1963876762 date "1988-01-01" @default.
- W1963876762 modified "2023-09-22" @default.
- W1963876762 title "Direct and alternating current voltammetry at an HMDE in solutions containing activated charcoal suspension" @default.
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- W1963876762 doi "https://doi.org/10.1016/0022-0728(88)80271-7" @default.
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