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- W1963920460 abstract "A simple electrostatic model permits the estimation of Auger parameter shifts of core-ionized atoms in compounds with respect to the free atom in the gas phase. It is shown that the Auger parameter shift is a function of the number, distance, electronic polarizability and local geometry of the nearest-neighbour ligands around the core-ionized atom. We have investigated the relationship between the Cu Auger parameter shifts and the nuclearity of Cu clusters entrapped in A zeolites. It is shown that our model is useful to estimate this dependence. The model has also been applied with success to rationalize Auger parameter data on small copper clusters supported on α-Al2O3 (0001) surfaces and polycrystalline ZnO and graphite. We demonstrate that the screening properties of metal bulk and clusters of very low nuclearity are very similar." @default.
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- W1963920460 date "1993-05-01" @default.
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- W1963920460 title "Application of the Auger parameter in the characterization of small copper particles supported on insulators" @default.
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- W1963920460 doi "https://doi.org/10.1016/0039-6028(93)91130-h" @default.
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