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- W196392326 abstract "Anhand eines sehr vereinfachten Modells für den n → π*—Übergang α,β-ungesättigter Ketone wird für nichteben aufgebaute Enone eine Beziehung zwischen dem Schraubungssinn des Chromophors und dem Vorzeichen des Circulardichroismus abgeleitet. Diese ist auf 6- und 7-gliedrige Ringe anwendbar. Bei Cyclohexenonen mit koplanarer Anordnung des Enonsystems determiniert das aus der Ringebene herausragende C-Atom den Cotton-Effekt, wie empirisch gefunden wurde. Using a very simplified model for the n → π*—transition of α,β-unsaturated ketones a relation is derived between the chirality of non planar chromophores and the sign of their circular dichroisms. This rule is applicable to 6- and 7-membered rings. With cyclohexenones with planar chromophores this C-atom that sticks out of the plane of the ring determines the Cotton effect, as has been found empirically." @default.
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- W196392326 date "1965-01-01" @default.
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- W196392326 title "Circulardichroismus—VIII" @default.
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- W196392326 doi "https://doi.org/10.1016/s0040-4020(01)98282-1" @default.
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