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• W1963939532 abstract "Through the use of first-principles Ge $K$-edge XANES simulations we demonstrate that the structure of melt-quenched amorphous Ge-Sb-Te is intrinsically complex and is a mixture of Ge(3):Te(3) and Ge(4):Te(2) configurations in comparable concentrations, in contrast to the as-deposited amorphous phase that is dominated by the Ge(4):Te(2) configurations. The reasons for Ge-Te polyvalency are discussed and it is argued that both configurations are compatible with the Mott 8--N rule and the definition of an ideal amorphous solid. The near-perfect Te-Te distance match between the two major configurations accounts for the high cyclability of phase-change materials. Stable compositions in the Ge-Sb-Te system are suggested." @default.
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• W1963939532 date "2011-02-11" @default.
• W1963939532 modified "2023-10-18" @default.
• W1963939532 title "Intrinsic complexity of the melt-quenched amorphous Ge<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow /><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Sb<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow /><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Te<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><…" @default.
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• W1963939532 doi "https://doi.org/10.1103/physrevb.83.054203" @default.
• W1963939532 hasPublicationYear "2011" @default.
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