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- W1963955761 startingPage "1522" @default.
- W1963955761 abstract "A new apparatus for intermittent illumination has been designed and applied to the system of methylene blue and trimethylamine. A frequency effect has been discovered and established to be genuine. Thus, when the frequency is raised, the rate constant for the buffered and for the non-buffered solution shows an increase of about forty percent, but in the former case, between 1 p.p.s. and 10 p.p.s., and in the latter one between 10 p.p.s. and 100 p.p.s. If it is assumed that a certain intermediate X absorbs light and induces the additional reaction, the extinction coefficient of X ought to be 104∼105 in order to interpret the observed effect. Hence, it is likely that the intermediate in question is not an intermediate in true sense of the word, but the ground state dye in a slightly modified state." @default.
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- W1963955761 date "1963-11-01" @default.
- W1963955761 modified "2023-09-26" @default.
- W1963955761 title "The Application of Intermittent Illumination to the Bleaching of Dye. II. The Methylene Blue-Amine System" @default.
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- W1963955761 doi "https://doi.org/10.1246/bcsj.36.1522" @default.
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