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• W1963965400 abstract "The electrical conductivity of single crystals of ammonium perchlorate has been studied from 25 to 180°C. Plots of log σT vs 1T show two linear regions, one from 25 to 100 and another from 100 to 180°C. Activation energies for the conduction processes in the low- and high-temperature regions are 0.12 and 1.04 eV, respectively. The conduction is a bulk process and not a surface mechanism. Conduction in the low-temperature region is predominantly due to the migration of protons and is sensitive to the concentration of interstitial H2O molecules which act as proton donor and acceptor sites. In the high-temperature region, conduction is due to migration of NH4+ through cation vacancies. Detailed mechanisms are postulated both for electrical conduction and for the electrode reactions." @default.
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• W1963965400 date "1976-01-01" @default.
• W1963965400 modified "2023-10-14" @default.
• W1963965400 title "The electrical conductivity of ammonium perchlorate single crystals" @default.
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• W1963965400 doi "https://doi.org/10.1016/0022-4596(76)90016-5" @default.
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