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- W1963968310 abstract "Kinetic studies, secondary α-deuterium kinetic isotope effects, primary chlorine kinetic isotope effects (1), Hammett ρ values determined by changing the substituent in the nucleophile, and activation parameters have been used to determine the detailed (relative) structures of the transition states for the S N 2 reactions between para-substituted benzyl chlorides and thiophenoxide ion. A rationale for the U-shaped Hammett ρ plots observed when para-substituted benzyl compounds react with negatively charged nucleophiles is also presented." @default.
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- W1963968310 date "1982-10-01" @default.
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- W1963968310 title "Isotope effects in nucleophilic substitution reactions. IV. The effect of changing a substituent at the α carbon on the structure of SN2 transition states" @default.
- W1963968310 doi "https://doi.org/10.1139/v82-360" @default.
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