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• W1963969159 endingPage "2283" @default.
• W1963969159 startingPage "2271" @default.
• W1963969159 abstract "The [Ni(S,N)2] complexes (S,N = 1,3-thiazolidine-2-thionato, tzdt, 1,3-thiazoline-2-thionato, tzt, and 2-mercaptobenzothiazolato, mbt) have been obtained in good yield by direct electrochemical oxidation of nickel in the presence of the corresponding ligand. The [Ni(tzdt)2] and [Ni(mbt)2] derivatives react with nitrogen donor bases to give the adducts [Ni(S,N)2(L)2] (L = substituted pyridines and primary amines) and [Ni(S,N)2L] (L = bpy, phen, dmp) also obtained by direct electrochemical synthesis. A crystal structure analysis shows that in [Ni(mbt)2(dmp)] the hexacoordinated environment of the nickel atom is formed by two bidentate mbt ligands and one dmp ligand." @default.
• W1963969159 created "2016-06-24" @default.
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• W1963969159 date "1994-08-01" @default.
• W1963969159 modified "2023-10-12" @default.
• W1963969159 title "Electrochemical synthesis and studies on the reactivity of heterocylic-thionato derivatives of nickel(II) with nitrogen donor bases" @default.
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• W1963969159 doi "https://doi.org/10.1016/s0277-5387(00)88137-1" @default.
• W1963969159 hasPublicationYear "1994" @default.
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