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• W1963998364 abstract "Quinaldine (2-methyl quinoline) is a liquid at room temperature, which can be supercooled to reach finally the glassy state. By heating the glass above the glass transition temperature Tg = 180 K the sample performs two subsequent transitions into, likewise, dielectrically active phases. Thus, the reorientational relaxations of these phases as well as the kinetics of the phase transitions can be tracked in a highly resolved way by dielectric spectroscopy. X-ray diffraction analysis clearly shows two structurally different crystalline phases in addition to the supercooled liquid. Calorimetric measurements support the notion of first order phase transitions, occurring irreversibly in the supercooled regime, and suggest that the intermediate crystalline phase is metastable, too. Analyzing the quite distinct dielectric relaxation strengths, we discuss the possible nature of the two crystalline phases. Additionally, a very similar behavior to quinaldine is observed for 3-methyl quinoline, indicating a broad field of polymorphism among the quinoline derivatives." @default.
• W1963998364 created "2016-06-24" @default.
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• W1963998364 date "2012-08-03" @default.
• W1963998364 modified "2023-09-25" @default.
• W1963998364 title "Quinaldine: Accessing two crystalline polymorphs via the supercooled liquid" @default.
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• W1963998364 doi "https://doi.org/10.1063/1.4738583" @default.
• W1963998364 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22894362" @default.
• W1963998364 hasPublicationYear "2012" @default.
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