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- W1964007719 endingPage "4727" @default.
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- W1964007719 abstract "Bisoxazolidine 1 is an effective ligand in the Me2Zn-promoted and the Cu(I)-catalyzed Henry reaction. While a wide range of nitroaldol products are obtained in high yields and ee’s in both cases, the replacement of dimethylzinc with copper(I) acetate results in a complete reversal of the sense of asymmetric induction. The Cu(I)-catalyzed enantioselective addition of nitromethane to methyl 4-oxobutanoate followed by hydrogenation and spontaneous lactamization gives (S)-5-hydroxypiperidin-2-one in 72% overall yield and 98% ee which compares favorably with previously reported methods." @default.
- W1964007719 created "2016-06-24" @default.
- W1964007719 creator A5081721254 @default.
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- W1964007719 date "2009-09-10" @default.
- W1964007719 modified "2023-10-18" @default.
- W1964007719 title "Asymmetric Copper(I)-Catalyzed Henry Reaction with an Aminoindanol-Derived Bisoxazolidine Ligand" @default.
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- W1964007719 doi "https://doi.org/10.1021/ol9018612" @default.
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