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• W1964076215 abstract "Three new one-dimensional azido-bridged metal(II) complexes with formula [M 2 (4-azidopyridine) 4 (μ 1,1 -N 3 ) 2 (μ 1,3 -N 3 ) 2 ] n (M = Ni, Co, Cd) have been structurally and magnetically characterized. Three one-dimensional azido-bridged metal(II) complexes, [Ni 2 (4-azpy) 4 (μ 1,1 -N 3 ) 2 (μ 1,3 -N 3 ) 2 ] n ( 1 ), [Co 2 (4-azpy) 4 (μ 1,1 -N 3 ) 2 (μ 1,3 -N 3 ) 2 ] n ( 2 ), and [Cd 2 (4-azpy) 4 (μ 1,1 -N 3 ) 2 (μ 1,3 -N 3 ) 2 ] n ( 3 ), (4-azpy = 4-azidopyridine) were synthesized and characterized by UV–Vis, IR spectroscopy and by single crystal diffraction. The three iso-structural complexes exhibit distorted octahedral geometry around the metal(II) centers, terminal 4-azidopyridine ligands in trans -dispositions and alternating doubly bridged EO- and doubly bridged EE-azido ligands giving rise to polymeric 1-D systems. The asymmetric nature of the azide groups is increasing from EE- via EO- to covalent bonded N 3 -group in the 4-azidopyridine ligand. The magnetic properties of complexes 1 and 2 are reported." @default.
• W1964076215 created "2016-06-24" @default.
• W1964076215 creator A5008280655 @default.
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• W1964076215 creator A5040983493 @default.
• W1964076215 creator A5064175131 @default.
• W1964076215 creator A5068557550 @default.
• W1964076215 creator A5088588759 @default.
• W1964076215 date "2015-01-01" @default.
• W1964076215 modified "2023-10-14" @default.
• W1964076215 title "Synthesis and characterization of three new 1-D polymeric [M2(4-azidopyridine)4(μ1,1-N3)2(μ1,3-N3)2]n (M=Ni, Co, Cd) complexes" @default.
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• W1964076215 doi "https://doi.org/10.1016/j.poly.2014.08.012" @default.
• W1964076215 hasPublicationYear "2015" @default.
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