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- W1964080989 abstract "Acidic ionic liquid ([BsAIm][OTf]) was immobilized on sulfhydryl-group-modified SiO2 (MPS-SiO2) via free radical addition reaction. The [BsAIm][OTf] loading on acidic ionic liquid-functionalized silica ([BsAIm][OTf]/SiO2) was controlled through tuning the sulfydryl (SH) content of MPS-SiO2. All the samples were characterized by FT-IR, elemental analysis, N2 adsorption-desorption measurements and TG-DTA. The catalytic performance of [BsAIm][OTf]/SiO2 in the esterification of oleic acid and the transesterification of glycerol trioleate for biodiesel production was investigated. The results showed that with the increase of [BsAIm][OTf] loading on SiO2 the specific surface area and pore volume of [BsAIm][OTf]/SiO2 decreased, and the pore diameter of [BsAIm][OTf]/SiO2 narrowed. In the esterificaiton of oleic acid, the oleic acid conversion increased with the increasing [BsAIm][OTf] loading. In the transesterification of glycerol trioleate, with the increasing [BsAIm][OTf] loading the glycerol trioleate conversion decreased and the selectivities to glycerol monooleate and methyl oleate increased." @default.
- W1964080989 created "2016-06-24" @default.
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- W1964080989 date "2014-01-01" @default.
- W1964080989 modified "2023-10-18" @default.
- W1964080989 title "Catalytic performance of acidic ionic liquid-functionalized silica in biodiesel production" @default.
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- W1964080989 doi "https://doi.org/10.1016/s2095-4956(14)60122-4" @default.
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