Matches in SemOpenAlex for { <https://semopenalex.org/work/W196408246> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W196408246 endingPage "68" @default.
- W196408246 startingPage "59" @default.
- W196408246 abstract "Abstract Vapour–liquid equilibria (VLE), liquid–liquid equilibria (LLE), and excess enthalpies (HE) of binary mixtures of perfluoro-n-hexane plus an ether (diethyl, dipropyl, dibutyl, butyl methyl, and butyl ethyl ether), have been determined using a head-space gas-chromatographic technique, a turbidimetric apparatus, and a heat-flow calorimeter, respectively. A recently designed titration technique and calculation procedure have been used to obtain HE from heats of solution. The observed liquid–liquid coexistence curves have been compared with those predicted by the activity coefficients γi and their temperature dependence. All mixtures are strongly endothermic (HE > 0) and show large positive deviations from ideality (GE > 0), which increase with the size of the ether. Molecular interactions have been examined by calculating and discussing solvation functions and Kirkwood–Buff (KB) integrals. Perfluorohexane proved to be an inert molecule that interacts with ethers more weakly than hexane." @default.
- W196408246 created "2016-06-24" @default.
- W196408246 creator A5032842720 @default.
- W196408246 creator A5049153797 @default.
- W196408246 creator A5082830032 @default.
- W196408246 creator A5084841296 @default.
- W196408246 date "2008-07-01" @default.
- W196408246 modified "2023-10-18" @default.
- W196408246 title "Thermodynamic study of perfluorohexane+ether mixtures" @default.
- W196408246 cites W1582458709 @default.
- W196408246 cites W1975423858 @default.
- W196408246 cites W1980448213 @default.
- W196408246 cites W1993614823 @default.
- W196408246 cites W1999761470 @default.
- W196408246 cites W2003035634 @default.
- W196408246 cites W2003165617 @default.
- W196408246 cites W2005314389 @default.
- W196408246 cites W2013449545 @default.
- W196408246 cites W2021321463 @default.
- W196408246 cites W2026563620 @default.
- W196408246 cites W2030841140 @default.
- W196408246 cites W2040760340 @default.
- W196408246 cites W2050897119 @default.
- W196408246 cites W2065756075 @default.
- W196408246 cites W2082020321 @default.
- W196408246 cites W57517009 @default.
- W196408246 doi "https://doi.org/10.1016/j.fluid.2008.04.021" @default.
- W196408246 hasPublicationYear "2008" @default.
- W196408246 type Work @default.
- W196408246 sameAs 196408246 @default.
- W196408246 citedByCount "21" @default.
- W196408246 countsByYear W1964082462012 @default.
- W196408246 countsByYear W1964082462013 @default.
- W196408246 countsByYear W1964082462015 @default.
- W196408246 countsByYear W1964082462016 @default.
- W196408246 countsByYear W1964082462019 @default.
- W196408246 countsByYear W1964082462022 @default.
- W196408246 crossrefType "journal-article" @default.
- W196408246 hasAuthorship W196408246A5032842720 @default.
- W196408246 hasAuthorship W196408246A5049153797 @default.
- W196408246 hasAuthorship W196408246A5082830032 @default.
- W196408246 hasAuthorship W196408246A5084841296 @default.
- W196408246 hasConcept C121332964 @default.
- W196408246 hasConcept C178790620 @default.
- W196408246 hasConcept C185592680 @default.
- W196408246 hasConcept C2780407432 @default.
- W196408246 hasConcept C43617362 @default.
- W196408246 hasConcept C97355855 @default.
- W196408246 hasConceptScore W196408246C121332964 @default.
- W196408246 hasConceptScore W196408246C178790620 @default.
- W196408246 hasConceptScore W196408246C185592680 @default.
- W196408246 hasConceptScore W196408246C2780407432 @default.
- W196408246 hasConceptScore W196408246C43617362 @default.
- W196408246 hasConceptScore W196408246C97355855 @default.
- W196408246 hasIssue "1-2" @default.
- W196408246 hasLocation W1964082461 @default.
- W196408246 hasOpenAccess W196408246 @default.
- W196408246 hasPrimaryLocation W1964082461 @default.
- W196408246 hasRelatedWork W1970855118 @default.
- W196408246 hasRelatedWork W2004791622 @default.
- W196408246 hasRelatedWork W2013624536 @default.
- W196408246 hasRelatedWork W2023380945 @default.
- W196408246 hasRelatedWork W2088669026 @default.
- W196408246 hasRelatedWork W2322096078 @default.
- W196408246 hasRelatedWork W2325716356 @default.
- W196408246 hasRelatedWork W2330424792 @default.
- W196408246 hasRelatedWork W2771862401 @default.
- W196408246 hasRelatedWork W2952971467 @default.
- W196408246 hasVolume "269" @default.
- W196408246 isParatext "false" @default.
- W196408246 isRetracted "false" @default.
- W196408246 magId "196408246" @default.
- W196408246 workType "article" @default.