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- W1964092018 abstract "Iron dissolution as well as hydrogen evolution was studied in HCl and HBr acetonitrile solutions in a concentration range between 2·8 × 10−4 M. Halide concentration was changed by adding lithium halide to some of the previous solution. Measurements were performed at 0·0°C.Current efficiency for a two-electron transfer was about 100 per cent for both anodic and cathodic reactions.Corrosion and kinetic parameters were obtained from the polarization curves performed under different experimental conditions. Tafel slopes of 2·3 × 2 RT/F were found for both anodic and cathodic reactions.A reaction mechanism for the anodic reaction is postulated on the basis of anion adsorption. An inhibitory effect, probably due to solvent adsorption at the electrode, occurs as the acid concentration decreases, affecting both the anodic and cathodic polarization curves." @default.
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- W1964092018 date "1976-04-01" @default.
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- W1964092018 title "Electrochemical behaviour of iron electrode in acidic acetonitrile solutions" @default.
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- W1964092018 doi "https://doi.org/10.1016/0013-4686(76)80017-5" @default.
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