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- W1964121710 abstract "A quasielastic light-scattering (QLS) technique was employed to investigate simple micelles and mixed micelles formed in taurocholate (TC) and TC−lecithin (L) solutions. When the size and polydispersity of simple TC micelles were nearly unchanged with total TC concentrations, the simple TC micelles were suggested to be all of a single size. According to the relationship between the total TC concentration and the TC monomer concentration, a monomer−micelle model predicted the aggregation number (n) and the critical micellar concentration (cmc) of simple TC micelles to be 5 and 10 mM. Based on Flory's theory, the scattered intensity, the TC monomer concentration, the molecular weights of simple TC micelles, and mixed TC−L micelles were estimated to be 2138 Da and 35 840 Da. Moreover, the interaction coefficients of simple TC micelles and mixed TC−L micelles were found to be 1.30 × 10-5 dL mol g-2 and 5.09 × 10-6 dL mol g-2. According to Flory's equation, the estimated interaction coefficients and the concentrations of simple TC micelles and mixed TC−L micelles resulted in different values of the proportionality constant. When the proportionality constant values were assumed to be unchanged, significant errors in the determined molecular weights of simple TC micelles and mixed TC−L micelles occurred." @default.
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- W1964121710 date "1997-09-01" @default.
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- W1964121710 title "Interactions and Molecular Weights of Simple Micelles and Mixed Micelles in Taurocholate and Taurocholate−Lecithin Solutions" @default.
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- W1964121710 doi "https://doi.org/10.1021/jp971692p" @default.
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