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- W1964133072 abstract "Copoly(ester-sulfonates) of varying compositions have been synthesized by interfacial polycondensation technique by using H2O–CHCl3 as an interphase, alkali as an acid acceptor and sodium lauryl sulfate-cetyl trimethyl ammonium bromide as mixed emulsifiers at 0 °C for 412 h. Copolymers are characterized by IR and NMR spectral data, viscosity in three different solvents at three temperatures and little solvent and temperature effect is found on [η]; and density (1.3430–1.3406 g/cm3) by floatation method. Copolymers possess excellent solubility in common solvents and chemical resistance against water, acids, alkalis and salts. They possess moderate to good tensile strength (10.6–79.5 N/mm2), excellent volume resistivity (7.5–28 × 1016 Ω cm), electric strength (53–118 kV/mm) and dielectric constant (1.3–1.58). They are thermally stable up to about 349–373 °C in an N2 atmosphere and possess high Tg (136–196 °C). DTA endo/exothermic transitions supported either decomposition or formation of new product(s). Physical properties of copolymers are improved with increasing terephthlate content." @default.
- W1964133072 created "2016-06-24" @default.
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- W1964133072 date "2004-02-01" @default.
- W1964133072 modified "2023-09-27" @default.
- W1964133072 title "Synthesis and physico-chemical properties of copoly(ester-sulfonates) of 1,1′-bis (3-methyl-4-hydroxy phenyl) cyclohexane with 2,4-toluene disulfonyl and terephthaloyl chlorides" @default.
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- W1964133072 doi "https://doi.org/10.1016/j.eurpolymj.2003.10.001" @default.
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