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- W1964208268 abstract "Fully anhydrous ion exchange into zeolite single crystals was attempted using nonaqueous solutions. Under various conditions, Na-A was exposed to flowing solutions of CuCl, CuCl2, and CuSO4 in acetonitrile and of CuCl2 in methanol. Na-A was treated with dimethyl sulfoxide solutions of Pb(NO3)2 and, at 140°C, KNO3. Finally, Na-A and Na-X were treated with HgS in liquid sulfur at 400°C. X-ray crystallography showed that in no case had any ion exchange occurred. Perhaps cations neither enter the zeolite nor leave sites within because their solvation complexes cannot hydrogen bond to framework oxygens." @default.
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- W1964208268 date "1995-05-01" @default.
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- W1964208268 title "Failure of ion exchange into zeolites A and X from four diverse nonaqueous solvents" @default.
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