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- W1964220824 abstract "The formation kinetics of the ions TMPD+ and pyrene+ have been studied in pulse irradiated dilute solutions of TPmPD and pyrene in cyclopentane, n-hexane, cyclohexane, methylcyclohexane, iso-octane and cyclo-octane. In cyclohexane and methylcyclohexane the rates of formation indicate rate constants, (7 ± 4) × 1011 M−1 sec−1 in the case of cyclohexane, for the reaction of solvent positive ions with the solute which are more than tenfold greater than expected for the reaction of molecular positive ions. In the other solvents, however, rate constants on the order of 1010 M−1sec−1 are found." @default.
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- W1964220824 date "1973-12-01" @default.
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- W1964220824 title "Anomalously high rate constants for the reaction of solvent positive ions with soluts in irradiated cyclohexane and methylcyclohexane" @default.
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- W1964220824 doi "https://doi.org/10.1016/0009-2614(73)85098-5" @default.
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