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• W1964236123 abstract "Abstract— The Haber-Weiss cycle: was investigated at low pH by radiolysis of oxygen or nitrogen saturated solutions of hydrogen peroxide. It was found that reaction 2 has a low rate constant: k2= 3.0 ± 0.6 M-1 s-1 (pH 2.3, 22°C). The rate determining step of reaction 2 is most probably the transfer of an electron from a π8* orbital of HO2 to the empty s̀u* orbital of H2O2. Overlap between these two orbitals is hindered by the filled π8* orbitals of H2O2. Fe(HI)EDTA catalyses reaction 2." @default.
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• W1964236123 date "1978-10-01" @default.
• W1964236123 modified "2023-10-05" @default.
• W1964236123 title "THE HABER-WEISS CYCLE" @default.
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• W1964236123 doi "https://doi.org/10.1111/j.1751-1097.1978.tb06989.x" @default.
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