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- W1964249583 abstract "Abstract: Intermediate 4 is unstable and rearranges into 5. Substitution of chlorine atoms in 5 by dialkylamino groups gives 8 and 9. 8 reacts with TEA to give phosphaalkene 10, which slowly dimerizes into 11. Methylenephosphinophosphorane 9 shows unusual properties. It adds isocyanates to two phosphorus atoms to give zwitterionic structural isomers 12a,b. The structure of 12a was resolved by X-ray analysis. 9 reacts with azides unexpectedly giving the zwitterionic product 13. Reaction of 9 with hexafluoroacetone is unusual and leads to the ylid 14a,b. According to the X-ray data it exists in zwitterionic form 14b and displays a new type of coordination at phosphorus atom. HFA can react in a similar way with other phosphines. For example, with 15 it gives the double ylid 16." @default.
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- W1964249583 date "1996-02-01" @default.
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- W1964249583 title "The Development of Improved Cationic Lipids for Gene Transfer Into Cystic Fibrosis Airway Epithelial Cells" @default.
- W1964249583 doi "https://doi.org/10.1080/10426509608046255" @default.
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