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• W1964256928 endingPage "12014" @default.
• W1964256928 startingPage "12007" @default.
• W1964256928 abstract "We present an ab initio study of the effects of boron incorporation in tetrahedral amorphous carbon using Car-Parrinello molecular dynamics. Samples of tetrahedral amorphous carbon at a density of $2.9{mathrm{g}/mathrm{c}mathrm{m}}^{3}$ with different boron contents (1.6% and 3.2%) have been generated by quenching from the liquid phase. We found that boron is mainly threefold coordinated and does not affect the fraction of fourfold coordinated carbon atoms, in agreement with experimental findings. Moreover, boron incorporation in highly stressed three-membered rings induces the opening of the ring which might provide a possible mechanism of the stress release observed experimentally upon boron doping. An analysis of the electronic properties reveals that boron does not induce shallow acceptor levels in the gap in any of the cases studied." @default.
• W1964256928 created "2016-06-24" @default.
• W1964256928 creator A5053628907 @default.
• W1964256928 creator A5081027867 @default.
• W1964256928 date "1999-11-01" @default.
• W1964256928 modified "2023-10-10" @default.
• W1964256928 title "<i>Ab initio</i>study of boron doping in tetrahedral amorphous carbon" @default.
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• W1964256928 doi "https://doi.org/10.1103/physrevb.60.12007" @default.
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