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• W1964257029 endingPage "09MC04" @default.
• W1964257029 startingPage "09MC04" @default.
• W1964257029 abstract "In this study, we investigated the sintering atmosphere dependence of the electric properties of Sn-doped (Ba 0.82 Ca 0.13 )TiO 3 ceramics to clarify the effect of Sn 2+ ions. The temperature of the dielectric constant peak for Sn-doped (Ba 0.82 Ca 0.13 )TiO 3 ceramics sintered in a low P (O 2 ) (1×10 -11 MPa) atmosphere is higher than that for the sample sintered in a high P (O 2 ) (2×10 -2 MPa) atmosphere. The remanent polarization and coercive field for the Sn-doped (Ba 0.82 Ca 0.13 )TiO 3 ceramics sintered at low P (O 2 ) (1×10 -11 MPa) also increased compared with those of the sample sintered at high P (O 2 ) (2×10 -2 MPa) at room temperature. The low P (O 2 ) sintering atmosphere for Sn-doped (Ba 0.82 Ca 0.13 )TiO 3 ceramics leads to a high tetragonality and the existence of Sn 2+ ions. In addition, by X-ray absorption spectroscopy, it was verified that Sn 2+ ions occupy Ba 2+ sites in the (Ba 0.82 Ca 0.13 )TiO 3 ceramics. Consequently, it is concluded that the high ferroelectric-to-paraelectric phase transition temperature and the high remanent polarization on the ceramics originate from Sn 2+ ions substituted for Ba 2+ sites in Sn-doped (Ba 0.82 Ca 0.13 )TiO 3 ceramics." @default.
• W1964257029 created "2016-06-24" @default.
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• W1964257029 date "2010-09-01" @default.
• W1964257029 modified "2023-10-16" @default.
• W1964257029 title "Effect of Sn²⁺ Ion Substitution on Dielectric Properties of (Ba,Ca)TiO₃ Ferroelectric Ceramics" @default.
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• W1964257029 doi "https://doi.org/10.1143/jjap.49.09mc04" @default.
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