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- W1964277972 abstract "THE discovery that carbon atom C4 of the cholesterol molecule is the first point of attack by oxygen, leading to the formation of cis ”5:6-cholestene-3: 4-diol, suggested that this reactive primary oxidation product may play an important role in the metabolism of cholesterol and the sexual hormones. Experimental confirmation of this view was obtained by feeding experiments, which showed that the diol, as well as its intermediate dehydration product cholestenone, were converted into coprosterol by the animal organism1. We have now obtained by mild oxidation of the 3 monoacetate (or 3-benzoate) of the cis-diol what is probably the oxide of 4-ketochole-stenol 3-acetate (or 3-benzoate). These compounds yield on hydrolysis a highly reactive substance C27H42O2 (I) which possesses the typical grouping —C = COH—CO— of diosphenol (buchu-camphor) (II)." @default.
- W1964277972 created "2016-06-24" @default.
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- W1964277972 date "1937-06-01" @default.
- W1964277972 modified "2023-09-27" @default.
- W1964277972 title "Cholesterol and the Adrenal Cortical Hormone" @default.
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- W1964277972 doi "https://doi.org/10.1038/1391015a0" @default.
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