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• W1964291226 endingPage "18163" @default.
• W1964291226 startingPage "18158" @default.
• W1964291226 abstract "The crystallization of sedimentating silica spheres in the presence of silica-coated boehmite rods in low-salt dimethylformamide is studied by means of confocal scanning laser microscopy. As expected, addition of rods gives rise to a net attraction due to the depletion effect. Upon increasing rod volume fractions, below a predicted equilibrium binodal, crystalline ordering of the spheres takes place faster but gives cause for more grain boundaries. Addition of rods at volume fractions in the theoretically predicted two-phase region gives rise to aggregation and glasslike sediments. We explain these results on the basis of the different gravitational lengths and sedimentation rate of both species: higher rod concentrations drive the system quicker into the two-phase region of the predicted phase-diagram." @default.
• W1964291226 created "2016-06-24" @default.
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• W1964291226 date "2004-10-28" @default.
• W1964291226 modified "2023-10-09" @default.
• W1964291226 title "Crystallization Kinetics and Morphology in Phase Separating and Sedimenting Mixtures of Colloidal Spheres and Rods" @default.
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• W1964291226 doi "https://doi.org/10.1021/jp0491515" @default.
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