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• W1964319794 startingPage "10130" @default.
• W1964319794 abstract "Nitrogen-doped microporous carbons (N-MCs) were prepared by the carbonization of the polyvinylidene fluoride (PVDF)/melamine mixture without chemical activation. The electrochemical performance of the N-MCs was investigated as a function of PVDF/melamine ratio. It was found that, without additional activation, the N-MCs had a high specific surface area (greater than 560 m2/g) because of the micropore formation by the release of fluorine groups. In addition, although the specific surface area decreased, nitrogen groups were increased with increasing melamine content, leading to an enhanced electrochemical performance. Indeed, the N-MCs showed a better electrochemical performance than that of microporous carbons (MCs) prepared by PVDF alone, and the highest specific capacitance (310 F/g) was obtained at a current density of 0.5 A/g, as compared to a value of 248 F/g for MCs. These results indicate that the microporous features of N-MC lead to feasible ion transfer during charge/discharge duration and the presence of nitrogen groups as strong electron donor on the N-MC electrode in electrolyte could provide a pseudocapacitance by the redox reaction." @default.
• W1964319794 created "2016-06-24" @default.
• W1964319794 creator A5075833583 @default.
• W1964319794 creator A5080823003 @default.
• W1964319794 date "2011-11-01" @default.
• W1964319794 modified "2023-09-24" @default.
• W1964319794 title "Synthesis of nitrogen doped microporous carbons prepared by activation-free method and their high electrochemical performance" @default.
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• W1964319794 doi "https://doi.org/10.1016/j.electacta.2011.08.107" @default.
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