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- W1964329197 abstract "A series of methano-C60 adducts bearing up to six electron donating N,N-dimethylaniline units (denoted as D compounds), along with their analogues without the dimethylamino groups as references (R compounds), were synthesized. The redox properties of the D compounds in solutions were evaluated spectroscopically in reference to the R compounds. According to UV/vis absorption results, there are obviously ground-state intramolecular charge-transfer complexes in the D series, and the charge-transfer effects apparently become saturated with only two donor units in the molecule. The photoinduced intramolecular electron-transfer properties of the D compounds were investigated via fluorescence measurements. The emission from intramolecular exciplexes can be found only in the D molecule with two electron donor units. Throughout the D series, the fluorescence properties are highly sensitive to the solvent polarity, with the emission completely quenched for all of the molecules in a polar solvent like methylene chloride. Mechanistic implications of the results are discussed." @default.
- W1964329197 created "2016-06-24" @default.
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- W1964329197 date "2005-05-26" @default.
- W1964329197 modified "2023-10-14" @default.
- W1964329197 title "Derivatized Fullerenes Bearing Multiple Electron Donors: Synthesis and Charge Transfer Properties" @default.
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- W1964329197 doi "https://doi.org/10.1021/jp044263h" @default.
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