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- W1964389479 abstract "Abstract The radical copolymerization of dichlorodifluoroethylene (CFE) with ethyl vinyl ether (EVE) has been studied. The two monomers form an alternating copolymer as indicated by elemental analysis. 19F NMR spectroscopy of CFE demonstrates the formation of a charge-transfer complex (K=0.056 1 mol−1). The structure of the copolymer was determined by studying the cotelomerization of the two monomers with a fluorinated mercaptan (C6F13CH2CH2SH). This reaction produced the monoadducts C6F13CH2CH2SCF2CCl2H and C6F13CH2CH2SCH2CH2OCH2CH3, and also the adduct 1,1′-C6F13CH2CH2SCF2CCl2CH2CH2OCH2CH3. This structure was determined by 1H and 13C NMR spectroscopy and is opposite to that expected from the charge-transfer complex. Thus it can be assumed that the copolymerization of the two monomers CFE and EVE involves the free monomers rather than propagation via the acceptor-donor complex. The alternating nature of the copolymer arises from the great difference in polarity between the two types of monomers." @default.
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- W1964389479 date "1995-07-01" @default.
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- W1964389479 title "Etude de la copolymérisation radicalaire alternée du dichlorodifluoroéthylène avec l'éthyl vinyl éther" @default.
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- W1964389479 doi "https://doi.org/10.1016/0022-1139(94)03191-2" @default.
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