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- W1964420439 abstract "Using 2,3,4,6-tetra-O-acetyl-β-d-glucopyranosyl cyanide as a precursor, methyl (methyl 3-deoxy-α-d-arabino-hept-2-ulopyranosid)onate (6) and its 2-deoxy analogue (10) were prepared. The synthesis involved an elimination of one molecule of acetic acid from C-2–C-3 and transformation of the CN group into COOMe, followed by methoxymercuration with subsequent reductive removal of the mercuri residue to give 6 or hydrogenation of the double bond to give 10. Phosphorylation of the 7-OH group led to the title compounds." @default.
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- W1964420439 date "1996-12-01" @default.
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- W1964420439 title "A novel chemical synthesis of a 3-deoxy-d-arabino-heptulosonic acid 7-phosphate (DAHP) derivative and its 2-deoxy analogue" @default.
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- W1964420439 doi "https://doi.org/10.1016/s0008-6215(96)90122-6" @default.
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