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- W1964446745 abstract "Abstract A pseudo-point charge model has been found from a calculation of the 4f/ligand charge penetration effects, in Er3+: Au within a more general recently developed many-body theory for crystal fields in metals. In this particular system contributions to crystal field parameters (CFP) directly from neighbours may be described in terms of a Coulomb interaction using different effective total charges on the ligands for the fourth order and sixth order components of the crystal field. It has been found that the penetration effects considerably enhance the CFP with respect to their point charge model (PCM) values. The sixth order CFP is much more affected than the fourth CFP by such effects. The calculation of these effective charges is presented in the absence of any contributions from 5d virtual bound states." @default.
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- W1964446745 date "1988-01-01" @default.
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- W1964446745 title "Contributions to crystal field parameters for Er3+: Au from ligand electrons and nuclei" @default.
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- W1964446745 doi "https://doi.org/10.1016/0378-4363(88)90277-x" @default.
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