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- W1964468246 abstract "The pentaamminecobalt(III) complex with the 3-cyano-2,4-pentanedionate anion coordinated through the nitrile nitrogen has been characterized by X-ray crystallography. The crystals of [(NH3)5CoNCacac](Cl)(ClO4)·2H2O are triclinic, space group P1, a = 10.245(2) Å, b = 14.071(4) Å, c = 6.971(2) Å, α = 90.03(3)°, β = 109.86(2)°, γ = 108.91(2)°, V = 887.1 Å3, Z = 2, Dc = 1.64 g cm−3, F(000) = 456, Mo-Kα radiation, λ = 0.71069 Å, μ(Mo-Kα) = 12.7 cm−1. The structure was determined by the heavy-atom method, and refined by block-diagonal least-squares calculations, R = 0.0537, Rw = 0.0607, for 2499 observed reflections. Principal dimensions are: CoN(NH3) trans to NCacac− 1.940(5), other CoN(NH3) 1.967(2), CoN(NCacac−) 1.911(5) Å. The pendant acac moiety is best described in terms of a delocalized bond network with, for example, CC distances in the range 1.44–1.52(1) Å. Several reactions involving this free acac group are also described including the preparation and characterization of the dimeric species pentaamminecobalt(III) - μ - (3 - cyano - 2,4 - pentanedionato) - bis(propylenediamine) cobalt(III) perchlorate." @default.
- W1964468246 created "2016-06-24" @default.
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- W1964468246 date "1986-01-01" @default.
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- W1964468246 title "Reactions and X-ray crystal structure of (3-cyano-2,4-pentanedionato-N)pentaamminecobalt(III) perchlorate chloride dihydrate" @default.
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- W1964468246 doi "https://doi.org/10.1016/s0277-5387(00)87141-7" @default.
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