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- W1964489322 abstract "A variety of pyrimidine C-nucleosides bearing branched-chain sugars can be synthesized starting from adequately substituted (1R*,6S*,7S*,8R*)-7,8-isopropylidenedioxy-3,9-dioxabicyclo[4.2.1]nonan-4-ones. The general procedure consists of condensation with t-butoxybis(dimethylamino) methane, giving the corresponding α-dimethylaminomethylene lactones, base-catalyzed heterocycle formation with urea, thiourea, or guanidine, and acid-promoted removal of the isopropylidene protective group. The overall transformation proceeds with retention of the stereochemistry to afford only C-β-glycosyl nucleoside structures." @default.
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- W1964489322 date "1983-09-01" @default.
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- W1964489322 title "Stereocontrolled General Synthesis of Pyrimidine<i>C</i>-Nucleosides Having Branched-chain Sugar Moieties" @default.
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- W1964489322 doi "https://doi.org/10.1246/bcsj.56.2680" @default.
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