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- W1964511251 abstract "Abstract Biodegradable trimethylolpropane [2‐ethyl‐2‐(hydroxymethyl)‐1,3‐propanediol] esters of rapeseed oil fatty acids were synthesized by transesterification with rapeseed oil methyl ester both by enzymatic and chemical means, both in bench and pilot scales. Nearly complete conversions were obtained with both techniques. A reduced pressure of about 2 to 5 kPa, to remove the methanol formed during transesterification, was critical for a high product yield. The quantity of added water was also critical in the biocatalysis. Candida rugosa lipase was used as biocatalyst and an alkaline catalyst in chemical transesterifications. In biocatalysis the maximum total conversion to trimethylolpropane esters of up to 98% was obtained at 42°C, 5.3 kPa, and 15% added water. The maximum conversion of about 70% to the tri‐ester was obtained at the slightly higher temperature of 47°C. The reaction time was longer in the biocatalysis, but considerably higher temperatures were required in chemical synthesis. In the chemical synthesis tri‐ester yields increased when the temperature was first held at 85 to 110°C for 2.5 h and subsequently increased to up to 120°C for 8 h. The trimethylolpropane esters obtained were tested as biodegradable hydraulic fluids and compared to commercially available hydraulic oils. The hydraulic fluids based on trimethylolpropane esters of rapeseed oil had good cold stability, friction and wear characteristics, and resistance against oxidation at elevated temperatures." @default.
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- W1964511251 date "1998-11-01" @default.
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- W1964511251 title "Transesterification of trimethylolpropane and rapeseed oil methyl ester to environmentally acceptable lubricants" @default.
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- W1964511251 doi "https://doi.org/10.1007/s11746-998-0094-8" @default.
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