Matches in SemOpenAlex for { <https://semopenalex.org/work/W1964547148> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W1964547148 endingPage "1689" @default.
- W1964547148 startingPage "1682" @default.
- W1964547148 abstract "Low-temperature irradiations of 1-phenylcyclohexene (PC6) yield two singlet state 2 + 2 photodimers and two 4 + 2 cycloadducts. The 4 + 2 adducts are not observed in low intensity lamp irradiations at room temperature but are produced in significant quantities when PC6 solutions are subjected to higher intensity laser irradiation. The results indicate a reaction mechanism involving two trans-PC6 molecules. The findings are consistent with earlier kinetic observations that the decay of trans-PC6 adopts a significant second-order component at lower temperatures. The transient−transient reaction also occurs under triplet-sensitized low-temperature/low-intensity or room temperature/high-intensity irradiation conditions. Triplet-sensitized irradiations also yield significant amounts of the 2 + 2 photodimers produced by attack of the PC6 triplet on its ground state. Quantum yield studies reveal that the rate of addition of 3PC6* to its ground state is in the range 0.28 to 4.0 × 105 L mol-1 s-1 consistent with t..." @default.
- W1964547148 created "2016-06-24" @default.
- W1964547148 creator A5026399740 @default.
- W1964547148 creator A5027483007 @default.
- W1964547148 creator A5079681304 @default.
- W1964547148 date "1996-01-01" @default.
- W1964547148 modified "2023-09-26" @default.
- W1964547148 title "Photodimerization of 1-Phenylcyclohexene. A Novel Transient−Transient Component" @default.
- W1964547148 cites W1966504417 @default.
- W1964547148 cites W1972362508 @default.
- W1964547148 cites W1978282667 @default.
- W1964547148 cites W1978306225 @default.
- W1964547148 cites W1987593892 @default.
- W1964547148 cites W2001796400 @default.
- W1964547148 cites W2002534443 @default.
- W1964547148 cites W2003280016 @default.
- W1964547148 cites W2008901286 @default.
- W1964547148 cites W2022607918 @default.
- W1964547148 cites W2044797241 @default.
- W1964547148 cites W2047602064 @default.
- W1964547148 cites W2049594529 @default.
- W1964547148 cites W2069038729 @default.
- W1964547148 cites W2092005763 @default.
- W1964547148 cites W2094058462 @default.
- W1964547148 cites W2095077569 @default.
- W1964547148 cites W2322800744 @default.
- W1964547148 cites W2949811685 @default.
- W1964547148 cites W2950657238 @default.
- W1964547148 cites W2952053228 @default.
- W1964547148 cites W2953221659 @default.
- W1964547148 cites W3005002442 @default.
- W1964547148 cites W3005446954 @default.
- W1964547148 cites W4240052356 @default.
- W1964547148 cites W4248411289 @default.
- W1964547148 doi "https://doi.org/10.1021/ja9533860" @default.
- W1964547148 hasPublicationYear "1996" @default.
- W1964547148 type Work @default.
- W1964547148 sameAs 1964547148 @default.
- W1964547148 citedByCount "8" @default.
- W1964547148 countsByYear W19645471482014 @default.
- W1964547148 countsByYear W19645471482016 @default.
- W1964547148 crossrefType "journal-article" @default.
- W1964547148 hasAuthorship W1964547148A5026399740 @default.
- W1964547148 hasAuthorship W1964547148A5027483007 @default.
- W1964547148 hasAuthorship W1964547148A5079681304 @default.
- W1964547148 hasConcept C121332964 @default.
- W1964547148 hasConcept C168167062 @default.
- W1964547148 hasConcept C185592680 @default.
- W1964547148 hasConcept C199360897 @default.
- W1964547148 hasConcept C2780799671 @default.
- W1964547148 hasConcept C41008148 @default.
- W1964547148 hasConcept C97355855 @default.
- W1964547148 hasConceptScore W1964547148C121332964 @default.
- W1964547148 hasConceptScore W1964547148C168167062 @default.
- W1964547148 hasConceptScore W1964547148C185592680 @default.
- W1964547148 hasConceptScore W1964547148C199360897 @default.
- W1964547148 hasConceptScore W1964547148C2780799671 @default.
- W1964547148 hasConceptScore W1964547148C41008148 @default.
- W1964547148 hasConceptScore W1964547148C97355855 @default.
- W1964547148 hasIssue "7" @default.
- W1964547148 hasLocation W19645471481 @default.
- W1964547148 hasOpenAccess W1964547148 @default.
- W1964547148 hasPrimaryLocation W19645471481 @default.
- W1964547148 hasRelatedWork W1975753664 @default.
- W1964547148 hasRelatedWork W1994913595 @default.
- W1964547148 hasRelatedWork W2010425030 @default.
- W1964547148 hasRelatedWork W2361039220 @default.
- W1964547148 hasRelatedWork W2362457244 @default.
- W1964547148 hasRelatedWork W2366296867 @default.
- W1964547148 hasRelatedWork W2383587353 @default.
- W1964547148 hasRelatedWork W2732289953 @default.
- W1964547148 hasRelatedWork W2752275290 @default.
- W1964547148 hasRelatedWork W2951844308 @default.
- W1964547148 hasVolume "118" @default.
- W1964547148 isParatext "false" @default.
- W1964547148 isRetracted "false" @default.
- W1964547148 magId "1964547148" @default.
- W1964547148 workType "article" @default.