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• W1964548531 startingPage "3899" @default.
• W1964548531 abstract "We report experimental and computational evidence that cationic N-heterocyclic carbene gold complexes with electron-rich cyclopropanes rearrange to produce Fischer gold carbene complexes in the gas phase, in analogy to long-known condensed-phase rearrangements of protonated cyclopropanes. Our results help to generalize the relationship between Lewis-acidic metal complexes of cyclopropanes, metallacyclobutanes and metal carbenes." @default.
• W1964548531 created "2016-06-24" @default.
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• W1964548531 date "2010-01-01" @default.
• W1964548531 modified "2023-10-01" @default.
• W1964548531 title "Gold carbenes via 1,2-dialkoxycyclopropane ring-opening: a mass spectrometric and DFT study of the reaction pathways" @default.
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• W1964548531 doi "https://doi.org/10.1039/c0cc00086h" @default.
• W1964548531 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20405086" @default.
• W1964548531 hasPublicationYear "2010" @default.
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