FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1964548872> ?p ?o ?g. }

• W1964548872 endingPage "89" @default.
• W1964548872 startingPage "79" @default.
• W1964548872 abstract "Bimetallic Pd–M/C catalysts (M = Bi, Pb) for the selective oxidation of glyoxal into glyoxalic acid were prepared either from inorganic salts or from acetate-type precursors. The bimetallic catalysts were found to be very active, confirming the promoting ability of both bismuth and lead in this reaction. The magnitude of their effect in terms of activity and selectivity was similar, and dependent on the preparation method and on the composition (optimum for ratios Pd:M = 1). The heavy elements could play their promoter role when introduced in solution in combination with a monometallic Pd/C catalyst. A kinetic treatment of the complex reaction scheme was carried out, and the rate constants for each step were determined. This showed that the reaction proceeds through a real heterogeneous mechanism involving the catalyst for the oxidation of glyoxal into glyoxalic acid and then, in a second step, into oxalic acid. The direct formation of oxalic acid from glyoxal could be neglected, and the formation of glycolic acid was confirmed to depend only on the pH. The absence of deactivation with our catalysts was also demonstrated. Correlations between the rate constants and some surface characteristics of the promoted catalysts were evidenced." @default.
• W1964548872 created "2016-06-24" @default.
• W1964548872 creator A5012490336 @default.
• W1964548872 creator A5035723985 @default.
• W1964548872 creator A5040777405 @default.
• W1964548872 creator A5081064244 @default.
• W1964548872 date "2005-01-01" @default.
• W1964548872 modified "2023-09-26" @default.
• W1964548872 title "Mechanistic and kinetic studies on glyoxal oxidation with Bi- and Pb-promoted Pd/C catalysts" @default.
• W1964548872 cites W1966733563 @default.
• W1964548872 cites W1983595497 @default.
• W1964548872 cites W1990315561 @default.
• W1964548872 cites W2005846344 @default.
• W1964548872 cites W2006615347 @default.
• W1964548872 cites W2008432828 @default.
• W1964548872 cites W2012311804 @default.
• W1964548872 cites W2016667724 @default.
• W1964548872 cites W2021605188 @default.
• W1964548872 cites W2030056002 @default.
• W1964548872 cites W2039458355 @default.
• W1964548872 cites W2044578914 @default.
• W1964548872 cites W2045958537 @default.
• W1964548872 cites W2059714813 @default.
• W1964548872 cites W2070017760 @default.
• W1964548872 cites W2084047508 @default.
• W1964548872 cites W2086711184 @default.
• W1964548872 cites W2113809225 @default.
• W1964548872 cites W2139567529 @default.
• W1964548872 cites W2154508532 @default.
• W1964548872 cites W2250112253 @default.
• W1964548872 cites W2950791883 @default.
• W1964548872 doi "https://doi.org/10.1016/j.molcata.2004.08.030" @default.
• W1964548872 hasPublicationYear "2005" @default.
• W1964548872 type Work @default.
• W1964548872 sameAs 1964548872 @default.
• W1964548872 citedByCount "25" @default.
• W1964548872 countsByYear W19645488722012 @default.
• W1964548872 countsByYear W19645488722014 @default.
• W1964548872 countsByYear W19645488722015 @default.
• W1964548872 countsByYear W19645488722016 @default.
• W1964548872 countsByYear W19645488722017 @default.
• W1964548872 countsByYear W19645488722018 @default.
• W1964548872 countsByYear W19645488722019 @default.
• W1964548872 countsByYear W19645488722020 @default.
• W1964548872 countsByYear W19645488722021 @default.
• W1964548872 countsByYear W19645488722023 @default.
• W1964548872 crossrefType "journal-article" @default.
• W1964548872 hasAuthorship W1964548872A5012490336 @default.
• W1964548872 hasAuthorship W1964548872A5035723985 @default.
• W1964548872 hasAuthorship W1964548872A5040777405 @default.
• W1964548872 hasAuthorship W1964548872A5081064244 @default.
• W1964548872 hasConcept C118792377 @default.
• W1964548872 hasConcept C121332964 @default.
• W1964548872 hasConcept C129652920 @default.
• W1964548872 hasConcept C13965031 @default.
• W1964548872 hasConcept C148898269 @default.
• W1964548872 hasConcept C161790260 @default.
• W1964548872 hasConcept C178790620 @default.
• W1964548872 hasConcept C179104552 @default.
• W1964548872 hasConcept C185592680 @default.
• W1964548872 hasConcept C2775920511 @default.
• W1964548872 hasConcept C2777603720 @default.
• W1964548872 hasConcept C2780472526 @default.
• W1964548872 hasConcept C2781346138 @default.
• W1964548872 hasConcept C43411465 @default.
• W1964548872 hasConcept C523546767 @default.
• W1964548872 hasConcept C533668322 @default.
• W1964548872 hasConcept C54355233 @default.
• W1964548872 hasConcept C62520636 @default.
• W1964548872 hasConcept C86803240 @default.
• W1964548872 hasConcept C93391505 @default.
• W1964548872 hasConceptScore W1964548872C118792377 @default.
• W1964548872 hasConceptScore W1964548872C121332964 @default.
• W1964548872 hasConceptScore W1964548872C129652920 @default.
• W1964548872 hasConceptScore W1964548872C13965031 @default.
• W1964548872 hasConceptScore W1964548872C148898269 @default.
• W1964548872 hasConceptScore W1964548872C161790260 @default.
• W1964548872 hasConceptScore W1964548872C178790620 @default.
• W1964548872 hasConceptScore W1964548872C179104552 @default.
• W1964548872 hasConceptScore W1964548872C185592680 @default.
• W1964548872 hasConceptScore W1964548872C2775920511 @default.
• W1964548872 hasConceptScore W1964548872C2777603720 @default.
• W1964548872 hasConceptScore W1964548872C2780472526 @default.
• W1964548872 hasConceptScore W1964548872C2781346138 @default.
• W1964548872 hasConceptScore W1964548872C43411465 @default.
• W1964548872 hasConceptScore W1964548872C523546767 @default.
• W1964548872 hasConceptScore W1964548872C533668322 @default.
• W1964548872 hasConceptScore W1964548872C54355233 @default.
• W1964548872 hasConceptScore W1964548872C62520636 @default.
• W1964548872 hasConceptScore W1964548872C86803240 @default.
• W1964548872 hasConceptScore W1964548872C93391505 @default.
• W1964548872 hasIssue "1" @default.
• W1964548872 hasLocation W19645488721 @default.
• W1964548872 hasOpenAccess W1964548872 @default.
• W1964548872 hasPrimaryLocation W19645488721 @default.
• W1964548872 hasRelatedWork W1964548872 @default.
• W1964548872 hasRelatedWork W1991722793 @default.
• W1964548872 hasRelatedWork W2041840250 @default.

• next