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- W1964549680 abstract "Abstract Propagation and chain‐length averaged termination rate coefficients, k p and < k t >, for radical polymerizations of methacrylates carrying poly(ethylene glycol) (PEG) units are reported. k p derived from pulsed laser initiated polymerizations in bulk, in organic solvents, and in ionic liquids follows the methacrylate‐type family behavior. Contrary, diffusion controlled k t values obtained from chemically initiated polymerizations with in‐line FT‐NIR monitoring of monomer conversion are strongly affected by the PEG units in the ester group. Compared to alkyl methacrylates < k t > is unexpectedly high. Moreover, < k t > of poly(ethylene glycol) ethyl ether methacrylate shows a significant reduction in k t already at 15% conversion, whereas dodecyl methacrylate < k t > is constant up to at least 70% conversion. magnified image" @default.
- W1964549680 created "2016-06-24" @default.
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- W1964549680 date "2010-02-26" @default.
- W1964549680 modified "2023-10-09" @default.
- W1964549680 title "Propagation and Termination Kinetics of PEGylated Methacrylate Radical Polymerizations" @default.
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- W1964549680 doi "https://doi.org/10.1002/macp.200900527" @default.
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