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- W1964555172 abstract "Permeation of ethylbenzene, styrene and cyclohexene through CR 61-CMP-447, a crosslinked-poly(sulfonated styrene) ion-exchange membrane, was investigated. The experiments were performed with single-component and bicomponent feeds with solute concentrations ranging from 0.5 to 2.0 M. The Na+-form membrane was highly permeable to the aromatics, while giving a much lower flux for cyclohexene. The magnitude of solute flux correlated well with the swelling degree of membrane by the solute. An additional experiment was carried out with the Na+-form membrane incorporated with poly(pyrrole) and 2.0 M styrene as a feed. The presence of poly(pyrrole) in the membrane resulted in a significant flux decline. As Ag+ ions were exchanged for Na+ ions, the solute fluxes were increased through the reversible complex formation. It was found that the solute flux attributed to the facilitated transport closely related to the diffusional flux. The styrene/ethylbenzene separation factors observed with single-component and bicomponent feeds were much the same, indicating a lack of competitive transport." @default.
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- W1964555172 date "2002-08-28" @default.
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- W1964555172 title "Facilitated transport of unsaturated hydrocarbons through crosslinked-poly(sulfonated styrene)" @default.
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- W1964555172 doi "https://doi.org/10.1016/s1385-8947(01)00243-1" @default.
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