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- W1964555866 abstract "We have studied both theoretically and experimentally the variation of NMR absorption lineshape as a function of nuclear polarization in systems with one spin species. General expressions are given for the first and second moments M1 and M1, as well as the values of M3 and M4 in the special case of spherical samples of spins 12 forming a simple cubic lattice. The influence of paramagnetic impurities on the line shape is analyzed, in detail. Measurements of M3 in spherical samples of CaF2 polarized up to 90% by the solid effect confirm the theory. In such samples the second moment, corrected from the effect of paramagnetic impurities, follows the simple law: M2(p) = M2(0) (1−p2). This has been used to perform an absolute calibration of fluorine polarization with an accuracy between 3 and 5%." @default.
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- W1964555866 date "1973-06-01" @default.
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- W1964555866 title "Absorption lineshape of highly polarized nuclear spin systems" @default.
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- W1964555866 doi "https://doi.org/10.1016/0022-2364(73)90253-9" @default.
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